D10. Define copolymer and discuss the benefit of copolymerization on polymer properties.

 

A copolymer is formed when two or more different monomers react during polymerization. For example, by mixing a dimethacrylate with a methacrylate, it is possible to cross-link polymer chains. Such a cross-linkage strengthens the polymer and decreases its solubility.

Copolymerization without cross-linking

 

`

 

Copolymerization with cross-linking

 

By combining different monomers and produce copolymers it is possible to "tailor-make" the final polymer. For example, by using a monomer in a copolymer that produces a long branch along the polymer chain, the back-bone chains will become more separated and the glass transition temperature can be decreased. Thus, a "softer" polymer is made. 

 


prev.gif (232 bytes)home.gif (253 bytes)next.gif (232 bytes)

E-mail: ksoderholm@dental.ufl.edu

© 1999, Karl-Johan M. Söderholm